The reaction of silver(I) ions with organic compounds containing the HN–CS grouping. Part II. Some thiourea derivatives
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 166-168
- https://doi.org/10.1039/j19660000166
Abstract
The formation of some sparingly soluble silver(I) complexes with thiourea and some of its derivatives (HL) is investigated. Thiourea, thiosemicarbazide, guanylthiourea, and dithiobiuret all give polymeric [Ag2(HL)3](NO3)2 species. Dithiobiuret also forms AgL in non-acidified solutions. Infrared studies are used to establish the bonding in the complexes.Keywords
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