Diastereoselective intramolecular SmI2–H2O–amine mediated couplings
- 18 June 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 1 (14) , 2423-2426
- https://doi.org/10.1039/b305428d
Abstract
The SmI2–H2O–amine mixture has been shown to be effective for intramolecular couplings providing diastereoselectivities of up to 100% de in the coupling of O-cyclohexenyliodophenol derivatives into heterocycles.Keywords
This publication has 33 references indexed in Scilit:
- Rapid SmI2-Mediated Reductions of Alkyl Halides and Electrochemical Properties of SmI2/H2O/AmineThe Journal of Organic Chemistry, 2003
- Instantaneous SmI2/H2O/Amine‐Mediated Reductions in THFChemistry – A European Journal, 2003
- Recent developments in lanthanide mediated organic synthesisJournal of the Chemical Society, Perkin Transactions 1, 2001
- Asymmetric Synthesis of β-Amino Alcohols by Cross-Pinacol Coupling of Planar Chiral Ferrocenecarboxaldehydes with IminesJournal of the American Chemical Society, 2000
- Radical Cyclization Reaction Using a Combination of Phosphinic Acid and a Base in Aqueous EthanolChemistry Letters, 2000
- Electrochemical Studies of Ni(cyclam)2+-Catalyzed Annulation ReactionsOrganometallics, 1998
- Reductions with Samarium(II) IodidePublished by Wiley ,1994
- Intramolecular reductive coupling reactions promoted by samarium diiodideJournal of the American Chemical Society, 1989
- Synthesis of Benzofuans, Tetrahydrobenzopyrans, and Related Cyclic Ethers via Cyclic CarbopalladationHETEROCYCLES, 1989
- Über die photochemische Cyclisierung von 2‐AllylphenolenHelvetica Chimica Acta, 1967