Catalysis by chlorohydridobis(triphenylphosphine)ruthenium(II) species. Novel kinetics and their implications for activation of saturated hydrocarbons
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 550-551
- https://doi.org/10.1039/c39770000550
Abstract
Novel kinetics for hydrogenation of acrylamide catalysed by [{HRuCl(PPh3)2}2] in solution indicate a mechanism which includes competitive oxidative addition reactions of H2 and propionamide (C–H cleavage) to ruthenium(I) centres.Keywords
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