Tantalum(III)
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 1,p. 87-89
- https://doi.org/10.1039/dt9720000087
Abstract
The reaction of tantalum tetrachloride with acetonitrile yields the diamagnetic dimer [TaCl3(MeCN)2]2. From these acetonitrile solutions similar diamagnetic complexes TaCl3(bipyridyl) and TaCl3(o-phenanthroline), and the paramagnetic tris (dibenzoylmethanato) tantalum(III) were prepared. These are the first compounds of tantalum (III) to be characterised.Keywords
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