The interaction of acyl halides and organosilicon hydrides catalysed by platinum and rhodium complexes. A new route to ketones
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 24,p. 1703-1704
- https://doi.org/10.1039/c29700001703
Abstract
Acyl halides react with triethylsilane in presence of certain platinum complexes to give aldhydes, but in the presence of rhodium catalysts (e.g. mer-[RhCl3(PBun 2-Ph)3]) formation of ketones can predominate.Keywords
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