Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 923-925
- https://doi.org/10.1039/c39840000923
Abstract
Azobenzenes are shown for the first time to exhibit substantial Li+ and Na+ cation effects on their electrochemical behaviour, and although K+ does not interact with Ar–NN–Ar, or its reduced form, a srong interaction is observed when K+ is bound as a cryptate complex.Keywords
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