Some amine-thiocyanate complexes of nickel(II)

Publisher Website
Google Scholar
Abstract
The preparation and properties of Ni(l,3-pn)2(NCS)2, Ni(trien)(NCS)2, Ni(tet a)(NCS)2, Ni(tet b)(NCS)2, Ni(dien)(NCS)2, Ni(dpt)(NCS)2, Ni(en)2NCSClO4, and Ni(trien)NCSClO4 are described (1,3-pn = 1,3-diaminopropane, trien = triethylenetetramine, tet a and tet b are isomeric hexamethylcyclotetradecanes, dien = diethylenetriamine, dpt = dipropylenetriamine, en = ethylenediamine). The first four compounds are normal N-bonded dithiocyanato derivatives, the dien and dpt derivatives have structures with one N-bonded terminal, and one bridging thiocyanate ion, and the thiocyanate perchlorate compounds have structures with a bridging thiocyanate ion. Magnetic susceptibilities (all μeff c. 3.1 B.M.), infrared spectra (including that of N-deuterated Si(l,3-pn)2(NCS)2), reflectance spectra, and conductances in methanol and acetone are reported.

This publication has 0 references indexed in Scilit: