Bent versus linear imido ligands in five-co-ordinate molybdenum complexes
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 22,p. 4197-4199
- https://doi.org/10.1039/dt9960004197
Abstract
A comparison of the molecular structures of the five-co-ordinate bis(imido) and imido alkylidene molybdenum complexes [Mo(NC6H3Pri 2-2,6)(L)(L′)], where L is a tridentate pyridinediolato ligand and L′ is either NC6H3Pri 2-2,6 or CHCMe2Ph, strongly supports the notion that the nitrogen of the bent imido ligand in the bis(imido) complex is sp2-hybridised.Keywords
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