Design, synthesis and structural investigation of a 2-D coordination network based on the self-assembly of the tetracarboxylate derivative of tetrathiacalix[4]arene and silver cation
- 1 November 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 22,p. 2219-2220
- https://doi.org/10.1039/b007761p
Abstract
The fully deprotonated tetrathiacalix[4]arene 14− in 1,3-alternate conformation and bearing four carboxylate units was shown to act as a tecton leading, in the presence of Ag+ cation, to a 2-D coordination network in the crystalline phase which can be described as discrete binuclear [14−, (Ag+)2]2− complexes interconnected by Ag+ cations.Keywords
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