Synthesis and Characterization of New Binuclear Co(0) Complexes with Diphosphinoamine Ligands. A Potential Approach for Asymmetric Pauson−Khand Reactions
- 27 April 1999
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 64 (10) , 3492-3497
- https://doi.org/10.1021/jo982245o
Abstract
The synthesis of P−N−P bidentate ligands and the evaluation, based on IR and X-ray data, of their π-acceptor properties in the complexes derived from phenylacetylene-dicobalt hexacarbonyl have been carried out. In addition, the reactivity of these complexes in the Pauson−Khand reaction has been examined.Keywords
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