Inorganic Supramolecular Host Architectures: [(M@18c6)2][TlI4]·2H2O, M = 0.5 Tl, (NH4,NH3), (H3O,H2O)
- 26 October 2005
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 44 (25) , 9340-9346
- https://doi.org/10.1021/ic051430z
Abstract
The compounds [(M@18c6)2][TlI4].2H2O, M=Tl, (NH4,NH3), (H3O,H2O) (cubic, Fd; a=1481.00 pm, for M=0.5 Tl, a=1304.65 pm for M=(NH4,NH3), a=1313.67 pm for M=(H3O,H2O)) can be obtained from solution in the presence of traces of transition metal halides (like copper and mercury halides). Apparently the transition metal cations work as a template in the form of tetrahedral [MX4] units during the synthesis of the supramolecular host architecture. That the compounds are versatile host lattices for tetrahedrally coordinated transition metal units becomes obvious by the large group of known host-guest complex compounds, [(MIIX4)(MI@18c6)4][TlX4]2.nH2O (MII=Cu, Co, Zn, Mn; MI=NH4+, Rb, Tl; X=Cl, Br).Keywords
This publication has 19 references indexed in Scilit:
- Lone Pair Effect in Thallium(I) Macrocyclic CompoundsInorganic Chemistry, 2005
- Crystal structure of an ammonium thiocyanate complex of 18–crown–6Crystal Research and Technology, 2004
- Unusual Luminescence Spectra and Decay Dynamics in Crystalline Supramolecular [(A18C6)4MBr4][TlBr4]2(A = Rb, K; M = 3d Element) ComplexesInorganic Chemistry, 1997
- Coordination Characteristics of Divalent Tetrahedral (Td and D2d) Tetrahalometalate Anions of 3d Elements and Solid-State 18C6 ReorientationsInorganic Chemistry, 1994
- Structure of the thallium-rich complex [(Tl18-crown-6)4CuBr4][TlBr4]2Acta Crystallographica Section C Crystal Structure Communications, 1993
- Immobilization of thallium by tandem oxidation/reduction-complexation of thallium(I/III)Inorganic Chemistry, 1992
- Ammonium chloride complexes with 18-crown-6Acta Crystallographica Section C Crystal Structure Communications, 1988
- Preparation and structure of bis(1,4,7,10,13,16-hexaoxacyclooctadecaneammonium) hexachlorouranate(IV)–acetonitrile (1/2), [(NH4)(18-crown-6)]2[UCl6].2CH3CNActa Crystallographica Section C Crystal Structure Communications, 1988
- Crystal structure analyses of 1,4,7,10,13,16-hexaoxacyclooctadecane and its complexes with alkali thiocyanatesActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1974
- Cyclic polyethers and their complexes with metal saltsJournal of the American Chemical Society, 1967