N.m.r. studies of some dimethylthallium compounds
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 67, 7-11
- https://doi.org/10.1039/tf9716700007
Abstract
The proton n.m.r. spectra of (Me2TlX)2(X = OEt, OBu-t, OPh, SMe, SO2Me, C5H5 and CCPh) have been observed. The methyl doublet in the dimethylthallium ethoxide spectra shows an unusual variation with temperature: tentative explanations are discussed. The variation of 2J(H…Tl) with mol ratio in mixtures of trimethylthallium and trimethylamine shows that this coupling constant has the same sign in Me3Tl and Me3Tl.NMe3.Keywords
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