Catalytic asymmetric allylation of aldehydes via a chiral indium(iii) complex
- 21 January 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1318-1320
- https://doi.org/10.1039/b412736f
Abstract
A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90–96% ee).Keywords
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