Substitution on five µ-oxo/µ-sulphido incomplete cuboidal MoIV3ions [Mo3OxS4–x(H2O)9]4+: kinetic effects resulting from the replacement of core oxo by sulphido ligands
- 1 January 1988
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1324-1325
- https://doi.org/10.1039/c39880001324
Abstract
A 570-fold spread in rate constants (25 °C), [H+]= 2.0 M, is observed for 1 : 1 NCS– substitution (of H2O) at Mo on the title complexes, with replacement of core µ3(O) by µ3(S) decreasing (factor of 10), and further replacement of the three µ2(O) by µ2(S) increasing (factor of 570) the rate of substitution.Keywords
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