DETERMINATION OF THE SECOND-HARMONIC-GENERATION COEFFICIENT AND THE LINEAR ELECTRO-OPTIC COEFFICIENT IN LiIO3 THROUGH OBLIQUE RAMAN PHONON MEASUREMENTS

Abstract
A new method for determing the second‐harmonic‐generation coefficient dijk and the linear electro‐optic term rijk as well as their relative sign from oblique phonon Raman‐scattering experiments is introduced. This method is applicable to piezoelectric crystals of orthorhombic or higher symmetry, where the oblique phonon cross section can be measured. The value of d13 and r13 for LiIO3 were determined.