Tryptophan Micro-Scale Determinations by Rapid Hydrolysis

Abstract
A rapid acid-hydrolysis micromethod was developed for the accurate determination of the tryptophan contents of proteins. Sample protein (5 .mu.g) was hydrolyzed in 30 .mu.l of 3 M mercaptoethanesulfonic acid at 166.degree. C for 25 min, resulting in total hydrolysis of the peptide bonds. The subjection of the hydrolysate to an amino-acid analyzer revealed the amino-acid composition, including the content of tryptophan with a high recovery of 92%.

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