Superoxide-bridged binuclear complexes of rhodium(III)
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2523-2526
- https://doi.org/10.1039/j19700002523
Abstract
The preparations are described of the blue or purple complex compounds of formulae [ClL4Rh·O2·RhL4Cl]Y3 where L = pyridine or γ-picoline and Y = an anion, and [(H2O)L4Rh·O2·RhL4(H2O)]Y5. The presence of the superoxide bridge is demonstrated by magnetic, spectroscopic, and analytical data. Acid-base equilibria for the aquo-complexes are mentioned. An account is given of the reduction forming the peroxo-bridged dimer [ClL4Rh·O2·RhL4Cl]Y2.Keywords
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