A calix[6]arene derived diphosphite, synthesis and complexation behaviour; X-ray structure of a palladium(II) chloride complex
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 583-584
- https://doi.org/10.1039/cc9960000583
Abstract
Calix[6]arene reacts with 2 equiv. of PCl3 to form a bidentate diphosphite ligand L which coordinates to Pd, Pt and Re in a cis fashion and, according to X-ray analysis, with a bite angle of approximately 90° for a palladium complex [PdCl2L].Keywords
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