Trimethylsilylcyanid
Open Access
- 1 March 1974
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung A
- Vol. 29 (3) , 513-517
- https://doi.org/10.1515/zna-1974-0324
Abstract
The gas-phase molecular structure of (CH3)3SiCN was determined by means of electron diffraction. The structural parameters are found to be: ra (Si-C≡) = 1.844±0.022 Å, ra (C ≡ N) = 1.170±0.007 Å, ra (Si - Cm) = 1.871 ± 0 .008 Å, ra (C-H ) = 1.111 ±0,009 Å, (∡ Cm- Si -C = ) = 107.0° ± 1.5 ° and (∡ Si - C - H ) = 110.4° ± 1.5°. The mole fraction of Isocyanide at 45 °C nozzle temperature was estimated to be smaller than 2%Keywords
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