B-2′-isoprenyldiisopinocampheylborane: An efficient reagent for the chiral isoprenylation of aldehydes. A convenient route to both enantiomers of ipsenol and ipsdienol
- 31 December 1990
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 31 (4) , 455-458
- https://doi.org/10.1016/0040-4039(90)87006-l
Abstract
No abstract availableKeywords
This publication has 29 references indexed in Scilit:
- Chiral synthesis via organoboranes. 14. Selective reductions. 41. Diisopinocampheylchloroborane, an exceptionally efficient chiral reducing agentJournal of the American Chemical Society, 1988
- Regiospecific functionalization of dimetalated isopropenylacetylene, a synthetic equivalent of the isoprene "anion". An efficient synthesis of the bark beetle pheromones (.+-.)-ipsenol and (.+-.)-ipsdienolThe Journal of Organic Chemistry, 1987
- Direct metallation of isopreneJournal of the Chemical Society, Chemical Communications, 1985
- Asymmetric synthesis via axially dissymmetric molecules. 6. Rational designing of efficient chiral reducing agents. Highly enantioselective reduction of aromatic ketones by binaphthol-modified lithium aluminum hydride reagentsJournal of the American Chemical Society, 1984
- Improved procedures for the synthesis of diisopinocampheylborane of high optical purityThe Journal of Organic Chemistry, 1984
- Hydroboration. 68. Chiral synthesis via organoboranes. 1. A simple procedure to achieve products of essentially 100% optical purity in hydroboration of alkenes with monoisopinocampheylborane. Synthesis of boronic esters and derived products of very high enantiomeric puritiesJournal of the American Chemical Society, 1984
- Facile regio- and stereo-specific allylic oxidation of gem-dimethyl olefins via addition of benzenesulphenyl chloride. Synthesis of allylic oxygenated terpenesJournal of the Chemical Society, Perkin Transactions 1, 1984
- New Three-Step Syntheses of Racemic and Optically Active Ipsdienol from Myrcene.Acta Chemica Scandinavica, 1983
- Selective inhibition of response of Ips pini to its pheromone by the (S)-(—)-enantiomer of ipsenolNature, 1977
- Access to Optically Active Ipsdienol from VerbenoneHelvetica Chimica Acta, 1977