Covalent compounds of quadrivalent transition metals. Part V. Molybdenum(IV) dialkylamides
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2741-2744
- https://doi.org/10.1039/j19710002741
Abstract
Tetrakis(dialkylamido)molybdenum(IV) compounds Mo(NR2)4(R = Me, Et) have been isolated from reactions of MoCl5 and LiNR2. The dimethylamide is a purple crystalline sublimable compound which is diamagnetic. The spectroscopic properties (electronic, vibrational, n.m.r.) are discussed in terms of a distorted tetrahedral configuration (D2d).Keywords
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