Solution and matrix photochemistry of (η-cyclopentadienyl)bis(ethane)rhodium
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1372-1374
- https://doi.org/10.1039/c39850001372
Abstract
Solution photolysis of (η-C5H5)Rh(C2H4)2 leads to substitution of ethane in the presence of donor ligands and to oxidative addition with R3SiH (R = Me or Et); photolysis in inert matrices causes reversible loss of ethane, but in reactive matrices substitution by N2 and CO takes place.Keywords
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