Preparation of an Electrically Conducting Polymer by the Electrolytic Polymerization of 3-Vinylperylene
- 1 October 1990
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics
- Vol. 190 (1) , 1-7
- https://doi.org/10.1080/00268949008047826
Abstract
An electrically conducting polymer was prepared by the controlled-potential anodic oxidation of 3-vinylperylene in a dichloromethane solution containing tetra-n-butylammonium perchlorate as a supporting electrolyte. The electrochemically-doped polymer is a partially oxidized radical-cation salt with ClO− 4 as a dopant; it exhibits a room-temperature conductivity up to 1 × 10−4 S cm−1 with an activation energy of ca. 0.3 eV.Keywords
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