Catalytic hydrogenation of nitriles and dehydrogenation of amines with the rhodium(I) hydrido compounds [RhH(PPri3)3] and [Rh2H2(µ-N2){P(cyclohexyl)3}4]
- 1 January 1979
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 870-871
- https://doi.org/10.1039/c39790000870
Abstract
[RhH(PPri 3)3] and [Rh2H2(µ-N2){P(cyclohexyl)3}4] are active catalysts for the hydrogenation of nitriles under ambient conditions, producing primary amines selectively; they are also active for the dehydrogenation of amines at higher temperatures to give nitriles or imines.Keywords
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