Alkylation of benzene with α-diazoketones via cycloheptatrienyl intermediates
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 491-492
- https://doi.org/10.1039/c39850000491
Abstract
Benzyl ketones can be synthesised efficiently from benzene and α-diazoketones with sequential catalysis by rhodium(II) trifluoroacetate and trifluoroacetic acids; the process involves cycloheptatrienyl intermediates.Keywords
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