Electronic structure of some oxyanions studied by X-ray emission and photoelectron spectroscopy

Abstract
The intensities of the X-ray emission spectra of a series of oxyanions are calculated using ab initio SCF MO wavefunctions, yielding good agreement with the experimental values. When combined with photoelectron spectra, these measurements may allow a definite assignment of the valence ionic states, as in the case of SO2– 4, studied here in detail.

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