The Radical Addition of Toluene to Fluorocyclobutenes
- 1 October 1977
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 50 (10) , 2815-2816
- https://doi.org/10.1246/bcsj.50.2815
Abstract
Fluorine-containing cyclobutane derivatives, 1-benzyl-1,2,2,3,3,4,-hexafluorocyclobutane (1) and 1,5,6,6,7,7-hexafluorobenzo[2,3]bicyclo[3.2.0]hept-2-ene (2), were synthesized in one step by the radical reaction of toluene and hexafluorocyclobutene. On the other hand, a similar reaction of toluene and 1,2-dichlorotetrafluorocyclobutene gave no adduct, but a substituted product, 1-benzyl-2-chlorotetrafluorocyclobutene (4).This publication has 7 references indexed in Scilit:
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