¹³C nuclear magnetic resonance of triacontacarbonyldodecarhodate(2–): [Rh₁₂(CO)₂₀(µ₂-CO)₂-(µ₃-CO)₈]^2–

1 January 1974

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 8,p. 310-311
https://doi.org/10.1039/c39740000310

Abstract

The ¹³C n.m.r. spectrum of [Rh₁₂(CO)₃₀]^2– is shown to be fully consistent with X-ray structural data and provides the first example of a triply bridging carbonyl resonance.

Keywords

NUCLEAR MAGNETIC RESONANCE

13C nuclear magnetic resonance of triacontacarbonyldodecarhodate(2–): [Rh12(CO)20(µ2-CO)2-(µ3-CO)8]2–

Abstract

Keywords

¹³C nuclear magnetic resonance of triacontacarbonyldodecarhodate(2–): [Rh₁₂(CO)₂₀(µ₂-CO)₂-(µ₃-CO)₈]^2–