Stereospecific Synthesis of Vinylsilanes via Trimethylsilyl-Substituted Allyliron Cations
- 1 January 1992
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1992 (12) , 973-975
- https://doi.org/10.1055/s-1992-21550
Abstract
The reaction of trimethylsilyl substituted anti- and syn-allyltetracarbonyliron complexes with silyl enol ethers, silyl ketene acetals, or allyltin compounds affords Z- and E-vinylsilanes, respectively, with a high degree of stereochemical purity.Keywords
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