A convenient synthesis of βγ-unsaturated carboxylic acids and esters. The isomeric 5-t-butylcyclohex-2-enecarboxylic acids
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 21,p. 2279-2280
- https://doi.org/10.1039/p19760002279
Abstract
A procedure is described for the conversion of six-membered ring allylic bromides via the corresponding nitriles into βγ-unsaturated acids and esters. In this way cis- and trans-5-t-butylcyclohex-2-enecarboxylic acids have been prepared. Configurations of the latter are assigned on the basis of hydrogenation to the known saturated acids.Keywords
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