The influence of ligand bite angle on the enantioselectivity of copper(II)-catalysed Diels–Alder reactions
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1753-1754
- https://doi.org/10.1039/cc9960001753
Abstract
Novel spirobis(oxazolines) provide excellent levels of stereocontrol in copper-catalysed Diels–Alder reactions; the larger the ligand bite angle the higher the enantioselection (up to 98.4% ee).Keywords
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