Kinetic spectroscopy in the far vacuum ultraviolet. Part 3.—Oscillator strengths for the 3S, 4S and 5S3S–2p43P2transitions in atomic oxygen
- 1 January 1976
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 72, 2178-2190
- https://doi.org/10.1039/f29767202178
Abstract
Line absorption measurements for ns3S–2p4 3PJ transitions have been made as a function of ground state oxygen O 2p4 3PJ atom concentration. The results gave the following values for the oscillator strengths (ƒik) of the ns3S–2p4 3P2 transitions of oxygen: (4.5 ± 1.0)× 10–2(n= 3, λ 130.22 nm); (5.9 ± 1.4)× 10–3(n= 4, λ 103.92nm); (1.5 ± 0.4)× 10–3(n= 5, λ 97.65nm). The agreement with the literature of the ƒ-value for n= 3 is good; no previous measurements for the n= 4 and n= 5 transitions appear to have been reported.Keywords
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