Reactions of boron, titanium, and tin halides with fluorinated nitriles
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 126-128
- https://doi.org/10.1039/j19680000126
Abstract
The reactions of trifluoromethyl and pentafluorophenyl cyanides with BCl3, BBr3, TiCl4, and SnCl4 have been investigated and the compounds [TiCl4(C6F5·CN)2], [BX3(C6F5·CN)], and {CF3·C(X)NBX2}2(X = Cl or Br) are described. The ethylideneamino-boranes were produced by the novel insertion of a cyano-group into a boron–halogen bond. 11B- and 19F-Nuclear magnetic resonance and infrared spectral data are recorded.Keywords
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