Enhancement of threo-selectivity in the reaction of but-2-enyl-lithium with aldehydes via allylic boronate complexes
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1072-1073
- https://doi.org/10.1039/c39800001072
Abstract
The threo-selectivity of the reaction of but-2-enyl-lithium with aldehydes in the presence of certain trialkylboranes is enhanced; the corresponding allylic boronate complexes are presumably involved as intermediates.Keywords
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