Secondary Deuterium Kinetic Isotope Effects in the Rotations of Alkenes and Allyl Radicals: Theory and Experiment
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 118 (4) , 886-892
- https://doi.org/10.1021/ja952046b
Abstract
No abstract availableKeywords
This publication has 36 references indexed in Scilit:
- Cleavage vs. rearrangement ratios and secondary deuterium kinetic isotope effects in the thermolysis of conformationally fixed cisoid vinylcyclobutanesThe Journal of Organic Chemistry, 1991
- An a b i n i t i o study of the structure and vibrational spectra of allyl and 1,4-pentadienyl radicalsThe Journal of Chemical Physics, 1990
- Ab initio calculations of the barrier to CF2 rotation in 1,1,3,3-tetrafluoropropenyl radicalThe Journal of Physical Chemistry, 1990
- An unusually large secondary deuterium isotope effect. Thermal trans-cis isomerization of trans-1-phenylcyclohexeneJournal of the American Chemical Society, 1987
- Thermal bridgehead double inversion of the 6-methylene- and 6-ethylidene-2-methylbicyclo[3.1.0]hexanes. Rotational kinetic deuterium isotope effects and the mechanism of the thermal interconversion of cis- and trans-2,3-dimethylmethylenecyclopropanes via trimethylenemethane singlet biradicalsJournal of the American Chemical Society, 1977
- Spectres de vibration et coordonnées normales de quatre espèces isotopiques de propèneSpectrochimica Acta Part A: Molecular Spectroscopy, 1973
- Simultaneity of allene cycloadditions. II. Dimerization of alleneJournal of the American Chemical Society, 1970
- A convenient gas chromatographic method for determining activation energies of first-order reactionsThe Journal of Organic Chemistry, 1968
- The tunnel effect correction for parabolic potential barriersTransactions of the Faraday Society, 1959
- Kinetics of Thermal Cis-Trans Isomerization. IIIJournal of the American Chemical Society, 1934