Structural model for the CuB site of dopamine β-hydroxylase and peptidylglycine α-hydroxylating monooxygenase: crystal structure of a copper(ii) complex showing N3OS coordination and axial sulfur ligation
- 23 November 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 24,p. 3553-3555
- https://doi.org/10.1039/b109332k
Abstract
A copper(II) complex [Cu(L)(phen)](ClO4) (HL, NSO-donor Schiff base ligand) with a CuIIN3OS geometry showing axial sulfur ligation is a structural model for the CuB site of DβH and PHM, and the complex is catalytically active in the oxidation of ascorbic acid by dioxygen mediated by a copper(I) species.Keywords
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