Reinterpretation of the Alkali Chloride Dissociation Rates of R. Hartig et al. as Cl− Collisional Detachment Rates
- 15 September 1971
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 55 (6) , 2922-2925
- https://doi.org/10.1063/1.1676516
Abstract
Thermal dissociation rates kd for various alkali chlorides have been published by Hartig et al. We have reinterpreted their results in terms of a collisional detachment rate for . Our interpretation implies a collisional detachment rate of by . Our reevaluation of their kd also removes the large disagreement between their measured rates and calculated values of the thermal dissociation rates of the alkali chlorides using the theory of Bates and Flannery.
Keywords
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