The Reactions of Copper(I) 1-Alkenyltrimethylborates with Allylic Bromides or 2-Propynyl Bromide
- 1 May 1980
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 53 (5) , 1471-1472
- https://doi.org/10.1246/bcsj.53.1471
Abstract
The reactions between copper(I) 1-alkenyltrimethylborates (readily obtainable from 2-(1-alkenyl)-1,3,2-benzodioxaboroles and methyllithium) and allylic bromides or 2-propynyl bromide were found to give corresponding coupling products. These reactions provide new synthetic routes to 1,4-alkadienes or 1,2,7-alkatrien-5-ynes.Keywords
This publication has 3 references indexed in Scilit:
- The Reaction of Copper(I) Methyltrialkylborates with 1-(1-Pyrrolidinyl)-6-chloro-1-cyclohexeneBulletin of the Chemical Society of Japan, 1979
- Addition Reaction of Copper(I) Methyltrialkylborates with Ethyl Propiolate. Stereospecific Synthesis of (E)-α,β-Unsaturated Acid EstersBulletin of the Chemical Society of Japan, 1977
- The Reaction of Copper(I) Methyltrialkylborates with Allylic Halides or 2-Propynylic HalidesBulletin of the Chemical Society of Japan, 1977