Cyanotrihydroborato- and tetrahydroborato-complexes of rhodium and iridium

Abstract
The synthesis and properties of air-stable hydroborato-complexes, trans-[MA(CO)(R3P)2][M = Ir, Rh; A = BH3(CN), BH4; R3P = tertiary phosphine] are reported; the co-ordination of BH3(CN), probably through the –NC group, is the first example of this anion acting as a ligand.

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