Metal–metal interaction in polynuclear silver(I) complexes: spectroscopy, luminescent properties and X-ray crystal structure of [Ag3(dppp)2(MeCN)2(ClO4)2]+[dppp = bis(diphenylphosphinophenylphosphine)]
- 1 January 1991
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1615-1617
- https://doi.org/10.1039/c39910001615
Abstract
The [Ag3(dppp)2(MeCN)2(ClO4)2]+ complex displays 1(dσ*→ pσ) transition at 288 nm and solid state photoluminescence at 467 nm; the Ag–Ag distances are 2.943–-3. 014 (2)Å.Keywords
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