Characterization of the Charge Transfer Complex from Furan and Maleic Anhydride and the Alternating Copolymer
- 1 January 1970
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 4 (1) , 51-63
- https://doi.org/10.1080/00222337008060965
Abstract
A previously unreported copolymer between furan and maleic anhydride was readily obtained by free radical initiation of benzene solutions of the comonomers. The product copolymers exhibit remarkably uniform composition regardless of monomer feed ratios. A donor-acceptor complex was suspected to account for the 1:1 alternating sequence of the monomers in the product. The complex was easily detected and partially characterized, although its exact role in the mechanism is uncertain.Keywords
This publication has 12 references indexed in Scilit:
- Solution Copolymerization of Styrene-Maleic Anhydride SystemThe Journal of the Society of Chemical Industry, Japan, 1967
- The Mechanism of the Copolymerization of Some Olefins with Maleic AnhydrideBulletin of the Chemical Society of Japan, 1965
- Radical Alternative Copolymerization of p-Dioxene and Maleic AnhydrideThe Journal of the Society of Chemical Industry, Japan, 1964
- The 1:1 copolymer of maleic anhydride and dihydropyranJournal of Polymer Science Part B: Polymer Letters, 1964
- Some comments on the Benesi‐Hildebrand equationRecueil des Travaux Chimiques des Pays-Bas, 1956
- Ultra-violet absorption and molecular complex formation of maleic anhydride in aromatic solventsTransactions of the Faraday Society, 1953
- A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic HydrocarbonsJournal of the American Chemical Society, 1949
- Copolymerization. IV. Effects of Temperature and Solvents on Monomer Reactivity RatiosJournal of the American Chemical Society, 1948
- The Polymerization of Allyl Compounds. III. The Peroxide-induced Copolymerization of Allyl Acetate with Maleic Anhydride1Journal of the American Chemical Society, 1946
- Complex Ions. I. The Identification of Complex Ions in Solution by Spectrophotometric MeasurementsJournal of the American Chemical Society, 1941