The geochemical stratigraphy, field relations and temporal variation of the Mull–Morvern Tertiary lava succession, NW Scotland

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Abstract
The early Tertiary Mull-Morvern lava succession, NW Scotland, represents the thickest continuous section (1000 m from sea level to the top of Ben More) of Tertiary lavas exposed in the UK. This succession has been sampled and geochemically analysed, on a flow-by-flow basis, throughout the lava succession. Field observations during the course of this sampling suggest that the early lava flows (the Staffa Magma sub-Type) ponded in palaeovalleys along with interlava sediments. In the main part of the Mull lava succession (the Mull Plateau Group) the lava flows are on average ∼ 5 m thick. Most previous Hebridean workers have assumed that the red horizons commonly found between these later lava flows, represent weathered flow tops. However, this study has shown that in some places these red ‘boles’ appear to be a combination of both volcanic ash and weathered basalt.Chemically distinctive units of flows have been found throughout the succession. The two most abundant magma sub-types of the Mull Plateau Group, primitive (>9wt% MgO) basalts with Ba/Nb» 15 and more evolved (<9wt% MgO) basalts-hawaiites with Ba/Nb<15, form packets of flow units which can be up to 200 m thick. These chemically distinctive flow units have been correlated across the lava succession. However, the correlation of individual lava flows has proved difficult. The Mull Plateau Group lavas generally become more evolved and less contaminated with continental crust towards the top of the succession, culminating in the trachytes of the Pale Group on Ben More. Basaltic lavas above the Pale Group have markedly different trace element ratios, and seem to represent shallower, more extensive asthenospheric melting than the Mull Plateau Group.