Mixed substrate supermolecules: binding of organic substrates and of metal ions to heterotopic coreceptors containing porphyrin subunits

Abstract
The macroteracyclic and macropentacyclic compounds (1)–(3), which combine porphyrin rings and [18]-N2O4aza-oxamacrocycles as substrate selective binding subunits, complex diammonium ions +H3N–[CH2]n–NH3+(anchored to the [18]-N2O4sites and included in the central molecular cavity) and /or ZnIIions (bound to the porphyrin groups), thus yielding organic/inorganic mixed substrate supramolecular structures.

This publication has 0 references indexed in Scilit: