Synthesen, chemische und elektrische Eigenschaften von Tetrathiafulvalen mit 1,6‐Methano[10]annulen‐Partialstruktur und von Chalcogendiimid‐derivaten
- 14 March 1984
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 67 (2) , 574-582
- https://doi.org/10.1002/hlca.19840670225
Abstract
Syntheses, Chemical and Electrical Properties of Tetrathiafulvalene with a 1,6‐Methano[10]annulene Moiety and of Chalcogendiimide‐DerivativesThe synthesis of the tetrathiafulvalene 6 has been described: the reaction of 1 with the benzenedithoil 2 yielded the bis‐dithioacetal 3 of 1,6‐methano[10]annulene‐dicarbaldehyde 1. The oxidation of 3 in the presence of HBF4 in Et2O yielded the salt 4, elimination of a hydride anion with triphenylmethylium tetrafluoroborate the salt 5, and elimination of a proton in 5 with Et3N the tetrathiafulvalene 6 with a 1,6‐methano[10]annulene moiety. The spectroscopic and electrochemical properties of 6 are described, and also the syntheses and properties of charge‐trasnfer complexes 7 and 8, including the properties of electric conductivity of 7 and 8. the syntheses of 9‐13 are reported and also their spectroscopic properties.Keywords
This publication has 22 references indexed in Scilit:
- Synthesen und chemische Eigenschaften neuer «Donor‐Akzeptor»‐stabilisierter Molekülsysteme mit zentraler Bicyclo [4.4.1]undeca‐l (10), 3,6,8‐tetraen‐2,5‐diyliden‐GruppeHelvetica Chimica Acta, 1982
- Synthesen von tetrathiafulvalen‐homologen Molekülsystemen mit zentraler Bicyclo [4.4.1]undeca‐1(10),3,5,8‐tetraen‐2,7‐diyliden‐ und Bicyclo [4.4.1]undeca‐1(10), 3,6,8‐tetraen‐2,5‐diyliden‐GruppeHelvetica Chimica Acta, 1982
- Synthesen und chemische Eigenschaften heterocyclisch‐substituierter 1,6‐Methano‐[10]annuleneEuropean Journal of Inorganic Chemistry, 1982
- Molecular, electronic, and crystal structure of naphtho[1,8-cd:4,5-c'd']bis[1,2,6]selenadiazineJournal of the American Chemical Society, 1980
- Synthesis of a Homologous Tetrathiafulvalene with Central Bicyclo[4.4.1]undeca‐1(10),3,5,8‐tetraene‐2,7‐diylidene GroupAngewandte Chemie International Edition in English, 1980
- Reaktionen von Schwefeldiimiden mit bifunktionellen Säurechloriden, II: Synthesen von 5‐Oxo‐5H‐1,3λ4,2,4‐dithiadiazol und 5‐Acylimino‐5H‐1,3λ4,2,4‐dithiadiazolenEuropean Journal of Inorganic Chemistry, 1978
- Massenspektroskopische Untersuchungen an 2,5‐Diaryl‐1‐(arylimino)‐1λ4,2,5‐thiadia‐zolidin‐3,4‐dionenJournal of Mass Spectrometry, 1977
- Reaktionen von Schwefeldiimiden mit bifunktionellen Säurechloriden, I. Synthese von 1λ4,2,5‐Thiadiazolidinen und ihren SulfoniumsalzenEuropean Journal of Inorganic Chemistry, 1977
- Synthesen von 2,5-Diorganyl-3,4-dioxo-1,2,5-thiadiazolidin-1-oxiden und 2,5-Diorganyl-3,4-dioxo-1,2,5-thiadiazolidinenSynthesis, 1977
- Alkylation of TlI Alkoxides. A Useful Modification of the Williamson EtherificationAngewandte Chemie International Edition in English, 1975