Flow-drift tube investigation of some Ar++ reactions
- 15 October 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 67 (8) , 3495-3499
- https://doi.org/10.1063/1.435346
Abstract
A new flow–drift technique for the investigation of ion–molecule reactions in the near thermal range, somewhat similar to the NOAA flow drift technique, is presented. Data on Ar+ reactions with H2, O2 and CO2 obtained to check the system agree well with recent NOAA results. The investigations of the first reactions of Ar++ with O2, CO2, and C2H2 show single charge transfers to be the only existing reaction channels, capture of two electrons by the Ar++ not being observed to occur. By contrast H2 showed no sign of reacting at all with Ar++ at rates within the range of these measurements.Keywords
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