Cobalt-59 Nuclear Magnetic Resonance Study of Cobalt(III) Complexes. Empirical Rules for the Cobalt-59 Chemical Shifts and Line Widths of [CoIII(en)x(NH3)6−2x−yLy]-type Complexes
- 1 June 1974
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 47 (6) , 1442-1446
- https://doi.org/10.1246/bcsj.47.1442
Abstract
The cobalt-59 chemical shifts and line widths for about seventy cobalt(III) complexes of the [CoIII(en)x(NH3)6−2x−yLy] (L= Cl, Br, NO2, N3, OH, H2O, CO3, and C2O4) type have been measured. The cobalt-59 chemical shifts of this type of complex are approximately represented by a simple relation:Keywords
This publication has 12 references indexed in Scilit:
- Cobalt-59 nuclear magnetic resonance study of isomerization reactions of mer- and fac-Co(en)(NH3)3OH2+ ions and trans-, cis,trans-, and cis,cis-Co(en)(NH3)2(OH)2+ ionsInorganic Chemistry, 1972
- Cobalt-59 nuclear magnetic resonance spectra of Unsymmetrical cobalt(III) complexesInorganica Chimica Acta, 1970
- The proton magnetic resonance spectra of cyclopentadiene trimers at 220 MHzMagnetic Resonance in Chemistry, 1969
- Nuclear magnetic resonance studies on cobalt complexes. I. Cobalt-59 nuclear magnetic resonance spectra of cobalt(III) complexes.Inorganica Chimica Acta, 1968
- Ligand Field Strengths of Xanthate and ThioxanthateThe Journal of Chemical Physics, 1967
- Kernquadrupolkopplung in einigen Kobalt(III)-komplexenTheoretical Chemistry Accounts, 1964
- Chemical Shifts in the Nuclear Magnetic Resonance of Co59 and the Ligand Field TheoryThe Journal of Chemical Physics, 1959
- Cobalt nuclear resonance spectraProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1957
- The Relation between the Geometrical Configurations of Inorganic Complexes and their Absorption Bands. III. A General Rule for the First and Second Bands of Co (III) ComplexesBulletin of the Chemical Society of Japan, 1952
- On the Nuclear Magnetic Moments of Several Stable IsotopesPhysical Review B, 1951