Theoretical studies of elementary excitations in liquid
- 1 November 1984
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 30 (9) , 5062-5075
- https://doi.org/10.1103/physrevb.30.5062
Abstract
Elementary excitations of liquid have been studied in the past with either perturbation theory in the basis of Feynman phonon states, or with variational theory using Feynman-Cohen (FC) wave functions. We develop perturbation theory in the basis of FC phonon states. Such a theory appears to have much better convergence. The second-order corrections to the FC spectrum are calculated, and these improve the agreement with experiment very significantly. We also calculate the strength of the collective mode. The second-order corrections to the of FC phonons also improve the agreement with experiment. Calculations are carried out at pressures of 0, 10, and 24 atm using the variational, Green's-function Monte Carlo and experimental pair distribution functions. Corrections to the Kirkwood superposition approximation for the three- and four-particle distribution functions are calculated with the variational ground-state wave functions containing pair and triplet correlations.
Keywords
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