Protonation of the decavanadate(6–) ion: a vanadium-51 nuclear magnetic resonance study
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 5,p. 503-506
- https://doi.org/10.1039/dt9780000503
Abstract
The first protonation site of [V10O28]6– differs both from the second protonation site and from the site of preferential interaction with aqueous manganese(II) ion. It is probably an out-of-plane apex, and not a bridging oxygen as has recently been proposed. The 51V n.m.r. linewidths are almost independent of direct protonation but depend in-directly on more distant protonation.Keywords
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