Formation of a Phospha-alkyne via Migration of the Phenyl Group from Phosphorus to Carbon
- 5 October 1988
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 17 (10) , 1733-1734
- https://doi.org/10.1246/cl.1988.1733
Abstract
E-2-Chloro-1-(2,4,6-tri-t-butylphenyl)-1-phospha-ethylene was allowed to react with t-butyllithium as a base to give 2-(2,4,6-tri-t-butylphenyl)-1-phospha-acetylene, suggesting the generation of a phosphorus analogue of isonitrile followed by migration of the phenyl group from phosphorus to carbon.Keywords
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