The Stereochemistry of Organometallic Compounds. XXXIII. Preparation and Reactions of Some Substituted Buta-1,3-Dienes

1 January 1989

journal article
Published by CSIRO Publishing in Australian Journal of Chemistry

Vol. 42 (4) , 471-478
https://doi.org/10.1071/ch9890471

Abstract

Hydroformylation and hydrocyanation of 2-methylhex-1-en-3-yne surprisingly both involve addition to the alkyne leading to the formation of formyl- and cyano-buta-1,3-dienes whose reactivity in Diels-Alder and ene-type reactions has been investigated.

Keywords

STEREOCHEMISTRY
XXXIII
COMPOUNDS
ORGANOMETALLIC
SURPRISINGLY
CYANO
ALDER
HYDROFORMYLATION

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